Photochemical decomposition of hydrogen peroxide (H2O2) and formaldehyde (HCHO) in artificial snow
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Photochemical decomposition of hydrogen peroxide (H2O2) and formaldehyde (HCHO) in artificial snow
Laboratory-made snow doped with either hydrogen peroxide (H2O2) or formaldehyde (HCHO) was exposed to radiation in the UV and visible range resulting in a decomposition of both compounds. These experiments demonstrate that besides the photolysis of nitrate further photochemical reactions of atmospheric relevant compounds can take place in snow. Under similar conditions the decomposition of H2O2...
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[1] Sensitivity studies with physically based numerical air–snow–firn transfer models for formaldehyde (HCHO) and hydrogen peroxide (H2O2) show that even though nonlinear processes determine the preservation of HCHO and H2O2 in snow and firn, changes in atmospheric mixing ratios are linearly recorded in ice cores under otherwise constant environmental conditions. However, temperature, snowpack ...
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Average H2O2 (HCHO) mixing ratios measured above the snowpack at South Pole (SP) were 278 pptv (103 pptv) in December 2000 and between 4 and 43 times (1.4–2.6 times) the value estimated from gas-phase photostationary state (PSS) model calculations. The larger difference is realized if dry deposition of both species is included in the model. H2O2 and HCHO fluxes from the snowpack were independen...
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Tower-based measurements of hydrogen peroxide (H2O2) and formaldehyde (HCHO) exchange were performed above the snowpack of the Greenland ice sheet. H2O2 and HCHO fluxes were measured continuously between 16 June and 7 July 2000, at the Summit Environmental Observatory. The fluxes were determined using coil scrubber-aqueous phase fluorometry systems together with micrometeorological techniques. ...
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Atmospheric hydroperoxides (ROOH) were measured at Summit, Greenland (72.97 N, 38.77 W) in summer 2003 (SUM03) and spring 2004 (SUM04) and South Pole in December 2003 (SP03). The two dominant hydroperoxides were H2O2 and CH3OOH (from here on MHP) with average (±1σ ) mixing ratios of 1448 (±688) pptv, 204 (±162) and 278 (±67) for H2O2 and 578 (±377) pptv, 139 (±101) pptv and 138 (±89) pptv for M...
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ژورنال
عنوان ژورنال: Annals of Glaciology
سال: 2004
ISSN: 0260-3055,1727-5644
DOI: 10.3189/172756404781814357